| 2025 | Duke 27O, 16 Virginia 20 | Darian Mensah, Duke |
| 2024 | 17 Clemson 34, 8 SMU 31 | Cade Klubnik, Clemson |
| 2023 | 4 Florida State 16, 14 Louisville 6 | Lawrance Toafili, Florida State |
| 2022 | 9 Clemson 39, 23 North Carolina 10 | Cade Klubnik, Clemson |
| 2021 | 15 Pittsburgh 45, 16 Wake Forest 21 | Erick Hallett, Pittsburgh |
| 2020 | 3 Clemson 34, 2 Notre Dame 10 | Trevor Lawrence, Clemson |
| 2019 | 3 Clemson 62, 22 Virginia 17 | Tee Higgins, Clemson |
| 2018 | 2 Clemson 42, Pittsburgh 10 | Travis Etienne, Clemson |
| 2017 | 1 Clemson 38, 7 Miami (FL) 3 | Kelly Bryant, Clemson |
| 2016 | 3 Clemson 42, 19 Virginia Tech 35 | Deshaun Watson, Clemson |
| 2015 | 1 Clemson 45, 8 North Carolina 37 | Deshaun Watson, Clemson |
| 2014 | Florida State 37, Georgia Tech 35 | Dalvin Cook (Florida State) |
| 2013 | Florida State 45, Duke 7 | Jameis Winston (Florida State) |
| 2012 | Florida State 21, Georgia Tech 15 | James Wilder, Jr. (Florida State) |
| 2011 | Clemson 38, Virginia Tech 10 | Tajh Boyd (Clemson) |
| 2010 | Virginia Tech 44, Florida State 33 | Tyrod Taylor (Virginia Tech) |
| 2009 | Georgia Tech 39, Clemson 34 | C. J. Spiller (Clemson) |
| 2008 | Virginia Tech 30, Boston College 12 | Tyrod Taylor (Virginia Tech) |
| 2007 | Virginia Tech 30, Boston College 16 | Sean Glennon (Virginia Tech) |
| 2006 | Wake Forest 9, Georgia Tech 6 | Sam Swank (Wake Forest) |
| 2005 | Florida State 27, Virginia Tech 22 | Willie Reid (Florida State) |
| 2004 | Virginia Tech 7-1-0 | | | |
| 2003 | Florida State 7-1-0 | | | |
| 2002 | Florida State 7-1-0 | | | |
| 2001 | Maryland 7-1-0 | | | |
| 2000 | Florida State 8-0-0 | | | |
| 1999 | Florida State 8-0-0 | | | |
| 1998 | Georgia Tech 7-1-0 | | | |
| 1998 | Florida State 7-1-0 | | | |
| 1997 | Florida State 8-0-0 | | | |
| 1996 | Florida State 8-0-0 | | | |
| 1995 | Virginia 7-1-0 | | | |
| 1995 | Florida State 7-1-0 | | | |
| 1994 | Florida State 8-0-0 | | | |
| 1993 | Florida State 8-0-0 | | | |
| 1992 | Florida State 8-0-0 | | | |
| 1991 | Clemson 6-0-1 | | | |
| 1990 | Georgia Tech 6-0-1 | | | |
| 1989 | Duke 6-1-0 | | | |
| 1989 | Virginia 6-1-0 | | | |
| 1988 | Clemson 6-1-0 | | | |
| 1987 | Clemson 6-1-0 | | | |
| 1986 | Clemson 5-1-0 | | | |
| 1985 | Maryland 6-0-0 | | | |
| 1984 | Maryland 5-0-0 | | | |
| 1983 | Maryland 5-0-0 | | | |
| 1982 | Clemson 6-0-0 | | | |
| 1981 | Clemson 6-0-0 | | | |
| 1980 | North Carolina 6-0-0 | | | |
| 1979 | North Carolina State 5-1-0 | | | |
| 1978 | Clemson 6-0-0 | | | |
| 1977 | North Carolina 5-0-1 | | | |
| 1976 | Maryland 5-0-0 | | | |
| 1975 | Maryland 5-0-0 | | | |
| 1974 | Maryland 6-0-0 | | | |
| 1973 | North Carolina State 6-0-0 | | | |
| 1972 | North Carolina 6-0-0 | | | |
| 1971 | North Carolina 6-0-0 | | | |
| 1970 | Wake Forest 5-1-0 | | | |
| 1969 | South Carolina 6-0-0 | | | |
| 1968 | North Carolina State 6-1-0 | | | |
| 1967 | Clemson 6-0-0 | | | |
| 1966 | Clemson 6-1-0 | | | |
| 1965 | North Carolina State 5-2-0 | | | |
| 1965 | Clemson 5-2-0 | | | |
| 1964 | North Carolina State 5-2-0 | | | |
| 1963 | North Carolina State 6-1-0 | | | |
| 1963 | North Carolina 6-1-0 | | | |
| 1962 | Duke 6-0-0 | | | |
| 1961 | Duke 5-1-0 | | | |
| 1960 | Duke 5-1-0 | | | |
| 1959 | Clemson 6-1-0 | | | |
| 1958 | Clemson 5-1-0 | | | |
| 1957 | North Carolina State 5-0-1 | | | |
| 1956 | Clemson 4-0-1 | | | |
| 1955 | Maryland 4-0-0 | | | |
| 1955 | Duke 4-0-0 | | | |
| 1954 | Duke 4-0-0 | | | |
| 1953 | Duke 4-0-0 | | | |
| 1953 | Maryland 3-0-0 | | | |
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